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Abstract. Ambient pine forest air was oxidized by OH, O3, or NO3 radicals using an oxidation flow reactor (OFR) during the BEACHON-RoMBAS (Bio–hydro–atmosphere interactions of Energy, Aerosols, Carbon, H2O, Organics and Nitrogen – Rocky Mountain Biogenic Aerosol Study) campaign to study biogenic secondary organic aerosol (SOA) formation and organic aerosol (OA) aging. A wide range of equivalent atmospheric photochemical ages was sampled, from hours up to days (for O3 and NO3) or weeks (for OH). Ambient air processed by the OFR was typically sampled every 20–30 min, in order to determine how the availability of SOA precursor gases in ambient air changed with diurnal and synoptic conditions, for each of the three oxidants. More SOA was formed during nighttime than daytime for all three oxidants, indicating that SOA precursor concentrations were higher at night. At all times of day, OH oxidation led to approximately 4 times more SOA formation than either O3 or NO3 oxidation. This is likely because O3 and NO3 will only react with gases containing C = C bonds (e.g., terpenes) to form SOA but will not react appreciably with many of their oxidation products or any species in the gas phase that lacks a C = C bond (e.g., pinonic acid, alkanes). In contrast, OH can continue to react with compounds that lack C = C bonds to produce SOA. Closure was achieved between the amount of SOA formed from O3 and NO3 oxidation in the OFR and the SOA predicted to form from measured concentrations of ambient monoterpenes and sesquiterpenes using published chamber yields. This is in contrast to previous work at this site (Palm et al., 2016), which has shown that a source of SOA from semi- and intermediate-volatility organic compounds (S/IVOCs) 3.4 times larger than the source from measured VOCs is needed to explain the measured SOA formation from OH oxidation. This work suggests that those S/IVOCs typically do not contain C = C bonds. O3 and NO3 oxidation produced SOA with elemental O : C and H : C similar to the least-oxidized OA observed in local ambient air, and neither oxidant led to net mass loss at the highest exposures, in contrast to OH oxidation. An OH exposure in the OFR equivalent to several hours of atmospheric aging also produced SOA with O : C and H : C values similar to ambient OA, while higher aging (days–weeks) led to formation of SOA with progressively higher O : C and lower H : C (and net mass loss at the highest exposures). NO3 oxidation led to the production of particulate organic nitrates (pRONO2), while OH and O3 oxidation (under low NO) did not, as expected. These measurements of SOA formation provide the first direct comparison of SOA formation potential and chemical evolution from OH, O3, and NO3 oxidation in the real atmosphere and help to clarify the oxidation processes that lead to SOA formation from biogenic hydrocarbons.

In a 1992 interview, Matthew Lipman affirmed that P4C was “a Deweyan way to go beyond Dewey” thereby explicitly acknowledging the Deweyan inspiration of his project but also asserting his own original contribution to the creation and development of a new educational approach. This achievement was the outcome of his effort to overcome what he later described as “the apparent inconsistency in Dewey’s formulation of the relationship between philosophy and education” (Lipman, 2008, p. 147). This inconsistency had been, indeed, the leading motivation for Lipman’s educational inquiry to the point that finding the solution to this problem would be his “life’s work” (p. ivi). Starting from this acknowledgment, the article highlights the Deweyan background of the P4C pedagogy, showing how Dewey’s ideas constitute a strong educational framework, which grounds and organizes both the curriculum and the device of the community of philosophical inquiry (COPI). However, it also identifies the original contributions offered by Lipman in the development of a new pedagogical framework, which successfully operationalizes a “practical” understanding of the educational role of philosophy. The focus is in particular on three elements within the P4C pedagogy, that represent Lipman’s original contribution to the development of the Deweyan legacy in accordance with a new pedagogical framework: the idea of teaching for thinking; the pattern of the process of inquiry in a P4C session; and the “reconstruction” of a new understanding of philosophy and its educational value, which constitutes the effective overcoming of the inconsistency that Lipman had found in Dewey’s educational thought.

Since the 1950's economists applied game theoretical concepts to a wide variety of economic problems. The Nash equilibrium concept has proven to be a powerful instrument in analyzing the outcome of economic processes. Since the late 1980's economists also show a growing interest in the application of evolutionary game theory. This paper discusses the main concepts of evolutionarygame theory and their applicability to economic issues. Whereas traditional game theory focusses on the static Nash equilibria as the possible outcomes of the game, evolutionary game theory teaches us to model explictly the behavior of individuals outside equilibrium. This may provide us with a better understanding of the dynamic forces within a society of interacting individuals.

Abstract Background The outbreak of the COVID-19 pandemic influenced family-centred care dramatically due to restricting visiting policies. In this new situation, nurses were challenged to develop new approaches to involve family members in patient care. A better understanding of these changes and the experiences of nurses is essential to make an adaptation of procedures, and to secure a family-centred approach in care as much as possible. Objectives The aim of this study was to investigate how family involvement had taken place, and to explore the experiences of nurses with family involvement during the COVID-19 outbreak. In addition, we aimed to formulate recommendations for the involvement of family. Methods We conducted a qualitative study using patient record review and focus-group interviews between April and July 2020. We reviewed records of patients with confirmed COVID-19, who were admitted to the COVID-19 wards at two affiliated university hospitals in the Netherlands. All records were searched for notations referring to family involvement. In two focus-groups, nurses who worked at the COVID-19 wards were invited to share their experiences. The Rigorous and Accelerated Data Reduction (RADaR) method was used to collect, reduce and analyse the data. Results In total, 189 patient records were reviewed and nine nurses participated in the focus-group meetings. Patient records revealed infrequent and often unstructured communication with focus on physical condition. Nurses confirmed that communication with family was far less than before and that the physical condition of the patient was predominant. The involvement of family in care was limited to practicalities, although more involvement was described in end-of-life situations. Nurses experienced moral distress due to the visiting restrictions, though some acknowledged that they had experienced the direct patient care so intense and burdensome, that family contact simply felt too much. Conclusion The communication with and involvement of family in hospital care changed enormously during the COVID-19 outbreak. Based on the identified themes, we formulated recommendations that may be helpful for family-centered care in hospitals during periods of restricted visiting policy.

Purpose: Land use in dry lands can result in a final stage where land is completely depleted or entirely degraded causing the desertification phenomenon. The first part (part 1) of this series of two articles proposed a methodology to include desertification in life cycle assessment (LCA). A set of variables to be measured in the life cycle inventory, characterization factors, and an impact assessment method for the life cycle impact assessment phase were proposed. This second part (part 2) aims at showing the application of the model proposed in part 1 on two case studies of agricultural activities. Methods: The impact model proposed is applied to plots of land devoted to agricultural activities in two countries: Argentina and Spain. In the agricultural plots of Spain (1SP to 9SP), two crops were analyzed: winter wheat (Triticum aestivum) and rapeseed (RS, Brassica napus). Two crops were considered in the Argentinean case study: rapeseed (RS, B. napus) and digit grass (Digitaria eriantha) (10AR to 17AR). A bare soil state is considered in both countries as a reference state. Both case studies consider only the agricultural stage in the inventory of a complete life cycle assessment study. Both also consider only one impact category in life cycle environmental assessment: desertification impact due to land occupation. Results and discussion: On the basis of the obtained results, it can be inferred that cultivating 1 ha of rapeseed and 1 ha of wheat has the same impact on the analyzed plots in Spain and improves the reference state conditions in 50 % of the cases. Moreover, rapeseed grown in Mendoza produces almost the same impact as in some of the Spanish plots. Normalized areas of plots could be useful to compare results in different regions of the world to avoid the influence of the area of occupation in results. Conclusions: The proposed model implies a contribution of significant importance because so far there has not been an impact assessment tool for land use in dry lands within the LCA framework. The main strength of the proposed model is that it allows a simple way to quantify the desertification impact. Also, it is emphasized that the model can be adapted virtually without difficulty to the evaluation of all types of crops with different management practices in different regions in the life cycle impact assessment stage. Fil: Civit, Bárbara María. Universidad Tecnológica Nacional. Facultad Regional de Mendoza; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mendoza. Instituto de Ciencias Humanas, Sociales y Ambientales; Argentina Fil: Arena, Alejandro Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico - Conicet - Mendoza. Instituto de Ciencias Humanas, Sociales y Ambientales; Argentina. Universidad Tecnológica Nacional. Facultad Regional de Mendoza; Argentina Fil: Nuñez, Monserrat. Institut d'investigació de la Generalitat de Catalunya; España Fil: Muñoz, Pere. Institut d'investigació de la Generalitat de Catalunya; España Fil: Antón, Assumpció. Institut d'investigació de la Generalitat de Catalunya; España Fil: Rieradevall, Joan. Universidad Autonoma de Barcelona; España

The ratio of branching fractions R(D∗-)≡B(B0→D∗-τ+ντ)/B(B0→D∗-μ+νμ) is measured using a data sample of proton-proton collisions collected with the LHCb detector at center-of-mass energies of 7 and 8 TeV, corresponding to an integrated luminosity of 3 fb-1. For the first time, R(D∗-) is determined using the τ-lepton decays with three charged pions in the final state. The B0→D∗-τ+ντ yield is normalized to that of the B0→D∗-π+π-π+ mode, providing a measurement of B(B0→D∗-τ+ντ)/B(B0→D∗-π+π-π+)=1.97±0.13±0.18, where the first uncertainty is statistical and the second systematic. The value of B(B0→D∗-τ+ντ)=(1.42±0.094±0.129±0.054)% is obtained, where the third uncertainty is due to the limited knowledge of the branching fraction of the normalization mode. Using the well-measured branching fraction of the B0→D∗-μ+νμ decay, a value of R(D∗-)=0.291±0.019±0.026±0.013 is established, where the third uncertainty is due to the limited knowledge of the branching fractions of the normalization and B0→D∗-μ+νμ modes. This measurement is in agreement with the standard model prediction and with previous results.

The “Warnock Report” (Department for Education and Science, 1978) underlined the importance of early intervention for children with a range of special educational needs and the importance of partnership with families. This paper focuses on young children with intellectual disability to describe the longitudinal research on early development that has emerged since the report, and to describe the scholarly literature that has been impacted by this longitudinal work. First, we conducted a systematic literature search for primary reports of longitudinal studies on the early development of children with intellectual disability. Included studies were those that measured dependent (i.e., developmental outcomes) and independent variables (i.e., risk and resilience factors) on at least two measurement occasions (i.e., truly longitudinal), starting before the end of the 7th year of life, with samples including children with intellectual disability (or related terms). The topics of these studies, and of the publications that have cited these longitudinal studies, were extracted from titles and abstracts using machine reading and subjected to multidimensional clustering (VOSviewer; Van Eck and Waltman, 2016). The resulting body of 101 research studies (about 2.5 studies per year) covered a scattering of topics without a dominant focus. The literature that was impacted by these longitudinal studies consisted of 3,491 scientific publications. Three clusters of topics emerged from mapping the terms used in these publications, which were dominated by (1) syndrome and disorder related terms; (2) autism-related terms; and (3) disability and parent related terms. Topics related to autism and, to a lesser extent, parents showed the strongest increase over time. Topics related to intervention and programmes were mostly linked to the topics disability and parents. Taking into account the science mapping as well as features of the context in which research on intellectual disability takes place, we suggest a collaborative research agenda that systematically links topics relevant for intervention with longitudinal research, in co-creation with families.

Thin potassium films grown on Si(001) substrates are used to measure internal chemicurrents and the external emission of exoelectrons simultaneously during adsorption of molecular oxygen on K surfaces at 120 K. The experiments clarify the dynamics of electronic excitations at a simple metal with a narrow valence band. X-ray photoemission reveals that for exposures below 5 L almost exclusively peroxide K2O2 is formed, i.e., no dissociation of the molecule occurs during interaction. Still a significant chemicurrent and a delayed exoelectron emission are detected due to a rapid injection of unoccupied molecular levels below the Fermi level. Since the valence band width of potassium is approximately equal to the potassium work function (2.4 eV) the underlying mechanism of exoemission is an Auger relaxation whereas chemicurrents are detected after resonant charge transfer from the metal valence band into the injected level. The change of the chemicurrent and exoemission efficiencies with oxygen coverage can be deduced from the kinetics of the reaction and the recorded internal and external emission currents traces. It is shown that the non-adiabaticity of the reaction increases with coverage due to a reduction of the electronic density of states at the surface while the work function does not vary significantly. Therefore, the peroxide formation is one of the first reaction systems which exhibits varying non-adiabaticity and efficiencies during the reaction. Non-adiabatic calculations based on model Hamiltonians and density functional theory support the picture of chemicurrent generation and explain the rapid injection of hot hole states by an intramolecular motion, i.e., the expansion of the oxygen molecule on the timescale of a quarter of a vibrational period.