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AbstractBasalt eruptions at Grímsvötn volcano, Iceland, are generally of low intensity; however, occasionally, an order of magnitude larger eruptions occur. In order to discuss the reasons for this difference, the degassing budget of S and Cl and crystallization conditions of the eruptive magma were determined from volatile concentration measured in melt inclusion (MI) and groundmass glass and thermobarometry, respectively. Tephra of two of the largest historical eruptions (2011 and 1873) and two much smaller eruptions (2004 and 1823) were investigated. Sulfur and Cl concentrations are higher in groundmass glass of the smaller eruptions due to incomplete outgassing caused by melt quenching in contact with glacial water. Sulfur concentration and degassing budget correlate with erupted magma volumes. Higher volatile concentrations of MI from the larger eruptions reflect important recharge of gas‐rich magma from depth. The recharge causes a high‐magnitude eruption followed by increased eruption frequency over the following decades. Pressure and temperature estimates of crystallization are obtained through equilibrium clinopyroxene‐glass pairs, where crystals adjacent to, and in textural equilibrium with, both groundmass glass and that of MI were measured. An average crystallization pressure of 4 ± 1 kbar corresponding to approximately 15 ± 5 km depth was obtained together with a considerable temperature range, 1065–1175°C. Similar crystallization depths are obtained for the basalt of the 2014–2015 Bárðarbunga rifting event and to a low resistivity layer revealed by magnetotelluric surveys. Therefore, an important magma storage depth is inferred at lower crustal depth above the center of the Iceland mantle plume.

AbstractVolcanic eruptions take place in Iceland about once every 3 to 5 years. Ash emissions from these eruptions can cause significant disruption to air traffic over Europe and the North Atlantic as is evident from the 2010 eruption of Eyjafjallajökull. Sulfur dioxide (SO2) is also emitted by volcanoes, but there are no criteria to define when airspace is considered hazardous or nonhazardous. However, SO2 is a well‐known ground‐level pollutant that can have detrimental effects on human health. We have used the United Kingdom Met Office's NAME (Numerical Atmospheric‐dispersion Modelling Environment) model to simulate SO2 mass concentrations that could occur in European and North Atlantic airspace for a range of hypothetical explosive eruptions in Iceland with a probability to occur about once every 3 to 5 years. Model performance was evaluated for the 2010 Eyjafjallajökull summit eruption against SO2 vertical column density retrievals from the Ozone Monitoring Instrument and in situ measurements from the United Kingdom Facility for Airborne Atmospheric Measurements research aircraft. We show that at no time during the 2010 Eyjafjallajökull eruption did SO2 mass concentrations at flight altitudes violate European air quality standards. In contrast, during a hypothetical short‐duration explosive eruption similar to Hekla in 2000 (emitting 0.2 Tg of SO2 within 2 h, or an average SO2 release rate 250 times that of Eyjafjallajökull 2010), simulated SO2 concentrations are greater than 1063 µg/m3 for about 48 h in a small area of European and North Atlantic airspace. By calculating the occurrence of aircraft encounters with the volcanic plume of a short‐duration eruption, we show that a 15 min or longer exposure of aircraft and passengers to concentrations ≥500 µg/m3 has a probability of about 0.1%. Although exposure of humans to such concentrations may lead to irritations to the eyes, nose and, throat and cause increased airway resistance even in healthy individuals, the risk is very low. However, the fact that volcanic ash and sulfur species are not always collocated and that passenger comfort could be compromised might be incentives to provide real‐time information on the presence or absence of volcanic SO2. Such information could aid aviation risk management during and after volcanic eruptions.

International audience; The interest in compound-specific isotope analysis for product authenticity control and source differentiation in environmental sciences has grown rapidly during the last decade. However, the isotopic analysis of very polar analytes is a challenging task due to the lack of suitable chromatographic separation techniques which can be used coupled to isotope ratio mass spectrometry. In this work, we present the first method to measure carbon isotope compositions of the widely applied herbicide glyphosate and its metabolite aminomethylphosphonic acid (AMPA) by liquid chromatography coupled to isotope ratio mass spectrometry. We demonstrate that this analysis can be carried out either in cation exchange or in reversed-phase separation modes. The reversed-phase separation yields a better performance in terms of resolution compared with the cation exchange method. The measurement of commercial glyphosate herbicide samples show its principal applicability and reveals a wide range of delta C-13 values between -24 and -34 aEuro degrees for different manufacturers. The absolute minimum amounts required to perform a precise and accurate determination of carbon isotope compositions of glyphosate and AMPA were in the sub-microgram range. The method proposed is sensitive enough to further perform the experiments that are necessary to better understand the carbon isotope fractionation associated to the natural degradation of glyphosate into AMPA. Furthermore, it can be used for contaminant source allocation and product authenticity as well.

In the hierarchical two-phase formation scenario, the extended halos of early type galaxies (ETGs) are expected to have different physical properties from those of the galaxies' central regions. This work aims at characterizing the kinematic properties of ETG halos using planetary nebulae (PNe) as tracers, which allow us to overcome the limitations of absorption line spectroscopy of continuum at low surface brightness. We present two-dimensional velocity and velocity dispersion fields for 33 ETGs, including both fast (FRs) and slow rotators (SRs), making this the largest kinematic survey to-date of extragalactic PNe. The velocity fields extend out to a median 5.6 effective radii (Re), with a range [3Re-13Re] for the PN.S ETGs. We complemented the PN kinematics with absorption line data from the literature. We find that ETGs typically show a kinematic transition between inner regions and halo. Estimated transition radii in units of Re anticorrelate with stellar mass. SRs have increased but still modest rotational support at large radii, while most of the FRs show a decrease in rotation, due to the fading of the stellar disk in the outer, more slowly rotating spheroid. 30% of the FRs are dominated by rotation also at large radii. Most ETGs have flat or slightly falling halo velocity dispersion profiles, but 15% of the sample have steeply falling profiles. 40% of the FRs show kinematic twists, misalignments, or rotation along two axes, indicating that they turn from oblate at the center to triaxial in the halo, consistently with the distribution of isophote twists from extended photometry. ETGs have more diverse kinematic properties in their halos than in the central regions. The observed kinematic transition to the halo and its dependence on stellar mass is consistent with LambdaCDM simulations and supports a two-phase formation scenario. [abridged] Comment: Accepted for publication in A&A, 52 pages, 30 figures

Glass materials are broadly used in the built environment (windows, facades, roofs, museum showcases, and solar panels) due to their optical (transparency) and thermal properties. Their interaction with the multiphase atmospheric medium results in a more or less pronounced transparency loss called soiling. This phenomenon leads to a loss of amenity of artefacts; consequently, high cleaning costs have to be supported by public and private entities. Complete understanding of the nature of surface deposit appears thus extremely important for addressing strategies to control it. The present research is based on the sheltered exposure, in different environments, of durable glass panels during 1 year. At these different locations, airborne pollutant concentrations have also been monitored. Three environments have been investigated: rural (R), urban (U) and industrial (I). Results show that the mass of the deposit and the optical impairment of the glass (haze) are too spread to allow discriminating between different environments. However, the analyses of soluble species and particulate organic matter allow identifying factors responsible for soiling and highlighted the reactivity of deposit to relative humidity which favours post-deposit evolution.

Abstract. We investigated the impact of drought on interannual variability of NPP from 1997 to 2009 using the standardized precipitation evapotranspiration index (SPEI) drought index and satellite-derived vegetation greenness converted net primary productivity (NPP). We found that SPEI and NPP were coupled and in phase on a global scale. We then used the Köppen climate classification to study the SPEI-NPP relations regionally and found that while NPP and SPEI were positively related in arid and in seasonal dry regions, the opposite occurs in most boreal regions. However, high intensity drought events, such as the 2003 drought in Europe, will lead to a reduction of NPP despite NPP being usually limited by temperature and radiation here. Our findings suggest that the strong positive relation between global average moisture availability and NPP is a composite of the positive relation across dry regions and the coherent NPP decline during and after intensive drought event in humid regions. The spatial patterns of drought impact on NPP could thus be categorized by climate classification, which implies that the predication of climate zone evaluation will contribute to the quantification of the future terrestrial carbon cycle.

The stable carbon isotope composition of dissolved inorganic carbon (δ13CDIC) in seawater was measured in a batch process for 552 samples collected during two cruises in the northeastern Atlantic and Nordic Seas from June to August 2012. One cruise was part of the UK Ocean Acidification research programme, and the other was a repeat hydrographic transect of the Extended Ellett Line. In combination with measurements made of other variables on these and other cruises, these data can be used to constrain the anthropogenic component of dissolved inorganic carbon (DIC) in the interior ocean, and to help to determine the influence of biological carbon uptake on surface ocean carbonate chemistry. The measurements have been processed, quality-controlled and submitted to an in-preparation global compilation of seawater δ13CDIC data, and are available from the British Oceanographic Data Centre. The observed δ13CDIC values fall in a range from −0.58 to +2.37 ‰, relative to the Vienna Pee Dee Belemnite standard. The mean of the absolute differences between samples collected in duplicate in the same container type during both cruises and measured consecutively is 0.10 ‰, which corresponds to a 1σ uncertainty of 0.09 ‰, and which is within the range reported by other published studies of this kind. A crossover analysis was performed with nearby historical δ13CDIC data, indicating that any systematic offsets between our measurements and previously published results are negligible. Data doi:10.5285/09760a3a-c2b5-250b-e053-6c86abc037c0 (northeastern Atlantic), doi:10.5285/09511dd0-51db-0e21-e053-6c86abc09b95 (Nordic Seas).